{"id":11578,"date":"2022-01-01T18:40:13","date_gmt":"2022-01-01T18:40:13","guid":{"rendered":"http:\/\/lequia-udg.com\/2022\/01\/01\/integrated-experimental-and-modeling-evaluation-of-removal-efficiency-and-energy-consumption-for-an-autotrophic-denitrifying-biocathode\/"},"modified":"2024-04-16T17:17:24","modified_gmt":"2024-04-16T17:17:24","slug":"integrated-experimental-and-modeling-evaluation-of-removal-efficiency-and-energy-consumption-for-an-autotrophic-denitrifying-biocathode","status":"publish","type":"post","link":"https:\/\/lequia-udg.com\/ca\/2022\/01\/01\/integrated-experimental-and-modeling-evaluation-of-removal-efficiency-and-energy-consumption-for-an-autotrophic-denitrifying-biocathode\/","title":{"rendered":"Integrated experimental and modeling evaluation of removal efficiency and energy consumption for an autotrophic denitrifying biocathode"},"content":{"rendered":"\t\t<div data-elementor-type=\"wp-post\" data-elementor-id=\"11578\" class=\"elementor elementor-11578 elementor-7058\" data-elementor-post-type=\"post\">\n\t\t\t\t\t\t<section class=\"elementor-section elementor-top-section elementor-element elementor-element-7b533f5d ts-col-stretched-none ts-bg-color-over-image elementor-section-boxed elementor-section-height-default elementor-section-height-default\" data-id=\"7b533f5d\" data-element_type=\"section\">\n\t\t\t\t\t\t<div class=\"elementor-container elementor-column-gap-default\">\n\t\t\t\t\t<div class=\"elementor-column elementor-col-100 elementor-top-column elementor-element elementor-element-2c6661ee ts-bg-color-over-image\" data-id=\"2c6661ee\" data-element_type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-58cb6c22 ts-align-left elementor-widget elementor-widget-ts_heading\" data-id=\"58cb6c22\" data-element_type=\"widget\" data-widget_type=\"ts_heading.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t<div class=\"ts-heading-subheading ts-reverse-heading-yes animation-style4\"><h4 class=\"ts-custom-heading ts-custom-subtitle\">\r\n\t\t\t\r\n\t\t\t\tAuthors: Cecconet, Daniele; Sabba, Fabrizio; Anastasi, Valentina; Bolognesi, Silvia; Callegari, Arianna; He, Zhen; Capodaglio, Andrea G.                                                                                                         \r\n\t\t\t\r\n\t\t\t<\/h4>\r\n\t\t<h2 class=\"ts-custom-heading ts-custom-heading-title\">\r\n\t\t\t\r\n\t\t\t\tIntegrated experimental and modeling evaluation of removal efficiency and energy consumption for an autotrophic denitrifying biocathode\r\n\t\t\t\r\n\t\t\t<\/h2>\r\n\t\t<\/div>\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t<section class=\"elementor-section elementor-top-section elementor-element elementor-element-6d740541 ts-col-stretched-none ts-bg-color-over-image elementor-section-boxed elementor-section-height-default elementor-section-height-default\" data-id=\"6d740541\" data-element_type=\"section\">\n\t\t\t\t\t\t<div class=\"elementor-container elementor-column-gap-default\">\n\t\t\t\t\t<div class=\"elementor-column elementor-col-100 elementor-top-column elementor-element elementor-element-212b987b ts-bg-color-over-image\" data-id=\"212b987b\" data-element_type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-6e8eba5a elementor-widget-tablet__width-initial elementor-widget elementor-widget-text-editor\" data-id=\"6e8eba5a\" data-element_type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<p>Nitrate (NO<sub>3<\/sub><sup>\u2212<\/sup>) contamination of groundwater is a worldwide issue that poses great threats to human health due to the use of the groundwater source for drinking water production. Among the available treatment technologies, bioelectrochemical systems (BESs) have emerged as an attractive treatment approach by using a cathode electrode as an electron donor for the reduction of nitrogen-forms (N-forms). In this work, a mathematical model for autotrophic biocathodic denitrification has been developed. This model successfully simulated both the denitrification process and the current demand by the system, allowing to predict and determine energy consumption related to the reduction of N-forms. The autotrophic denitrification model employed reduced electron carriers (mediators) where each denitrification step competes for the same electron pool based on different electron affinities. This approach allowed to model the exchange of electrons between the cathode and the terminal electron acceptors (TEAs) and the competition for electrons between NO<sub>3<\/sub><sup>\u2212<\/sup>\u00a0and nitrite (NO<sub>2<\/sub><sup>\u2212<\/sup>). The current demand was modeled considering two different contributions, namely an electrochemical part and the availability of TEAs in the cathodic chamber. The model was successfully calibrated and validated, and it was able to estimate the current demand, therefore allowing for an estimation of the energy consumption of the BES. A sensitivity analysis showed that the maximum NO<sub>2<\/sub><sup>\u2212<\/sup>\u00a0removal rate and the affinity constant of the reduced mediator for NO<sub>2<\/sub><sup>\u2212<\/sup>\u00a0were the key parameters affecting more the removal of total nitrogen in the model. Altogether our model provides a platform to accurately estimate removal efficiency and energy consumption in autotrophic denitrifying biocathodes.<\/p>\n\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t<section class=\"elementor-section elementor-top-section elementor-element elementor-element-bc3055e ts-col-stretched-none ts-bg-color-over-image elementor-section-boxed elementor-section-height-default elementor-section-height-default\" data-id=\"bc3055e\" data-element_type=\"section\">\n\t\t\t\t\t\t<div class=\"elementor-container elementor-column-gap-default\">\n\t\t\t\t\t<div class=\"elementor-column elementor-col-100 elementor-top-column elementor-element elementor-element-6204c649 ts-bg-color-over-image\" data-id=\"6204c649\" data-element_type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-5102a7c8 elementor-widget elementor-widget-accordion\" data-id=\"5102a7c8\" data-element_type=\"widget\" data-widget_type=\"accordion.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t<div class=\"elementor-accordion\">\n\t\t\t\t\t\t\t<div class=\"elementor-accordion-item\">\n\t\t\t\t\t<div id=\"elementor-tab-title-1351\" class=\"elementor-tab-title\" data-tab=\"1\" role=\"button\" aria-controls=\"elementor-tab-content-1351\" aria-expanded=\"false\">\n\t\t\t\t\t\t\t\t\t\t\t\t\t<span class=\"elementor-accordion-icon elementor-accordion-icon-left\" aria-hidden=\"true\">\n\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t<span class=\"elementor-accordion-icon-closed\"><i class=\"fas fa-plus\"><\/i><\/span>\n\t\t\t\t\t\t\t\t<span class=\"elementor-accordion-icon-opened\"><i class=\"fas fa-minus\"><\/i><\/span>\n\t\t\t\t\t\t\t\t\t\t\t\t\t\t<\/span>\n\t\t\t\t\t\t\t\t\t\t\t\t<a class=\"elementor-accordion-title\" tabindex=\"0\">Informaci\u00f3 addicional<\/a>\n\t\t\t\t\t<\/div>\n\t\t\t\t\t<div id=\"elementor-tab-content-1351\" class=\"elementor-tab-content elementor-clearfix\" data-tab=\"1\" role=\"region\" aria-labelledby=\"elementor-tab-title-1351\"><table style=\"border: hidden;\">\n<tbody>\n<tr style=\"border-bottom: 1px solid #efefef;\">\n<td align=\"right\" width=\"200\"><strong>Year:<\/strong><\/td>\n<td>2022<\/td>\n<\/tr>\n<tr style=\"border-bottom: 1px solid #efefef;\">\n<td align=\"right\" width=\"200\"><strong>Authors:<\/strong><\/td>\n<td>Cecconet, Daniele; Sabba, Fabrizio; Anastasi, Valentina; Bolognesi, Silvia; Callegari, Arianna; He, Zhen; Capodaglio, Andrea G.<\/td>\n<\/tr>\n<tr style=\"border-bottom: 1px solid #efefef;\">\n<td align=\"right\" width=\"200\"><strong>Reference:<\/strong><\/td>\n<td>Environmental Science: Water Research and Technology, Volume 8, Issue 7, Pages 1466 &#8211; 147726, May 2022<\/td>\n<\/tr>\n<tr style=\"border-bottom: 1px solid #efefef;\">\n<td align=\"right\" width=\"200\"><strong>Link:<\/strong><\/td>\n<td><a href=\"http:\/\/dx.doi.org\/10.1039\/d2ew00165a\" target=\"_blank\" rel=\"noopener\">http:\/\/dx.doi.org\/10.1039\/d2ew00165a<\/a><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<div class=\"elementor-element elementor-element-7b1e5c89 elementor-widget elementor-widget-spacer\" data-id=\"7b1e5c89\" data-element_type=\"widget\" data-widget_type=\"spacer.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t<div class=\"elementor-spacer\">\n\t\t\t<div class=\"elementor-spacer-inner\"><\/div>\n\t\t<\/div>\n\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t<\/div>\n\t\t","protected":false},"excerpt":{"rendered":"<p>Authors: Cecconet, Daniele; Sabba, Fabrizio; Anastasi, Valentina; Bolognesi, Silvia; Callegari, Arianna; He, Zhen; Capodaglio, Andrea G. Integrated experimental and modeling evaluation of removal efficiency and energy consumption for an autotrophic denitrifying biocathode Nitrate (NO3\u2212) contamination of groundwater is a worldwide issue that poses great threats to human health due to the use of the groundwater &hellip; <a href=\"https:\/\/lequia-udg.com\/ca\/2022\/01\/01\/integrated-experimental-and-modeling-evaluation-of-removal-efficiency-and-energy-consumption-for-an-autotrophic-denitrifying-biocathode\/\" class=\"more-link\" title=\"Continue reading <span class=\"screen-reader-text\">Integrated experimental and modeling evaluation of removal efficiency and energy consumption for an autotrophic denitrifying biocathode<\/span>&#8220;>Continue reading <span class=\"screen-reader-text\">Integrated experimental and modeling evaluation of removal efficiency and energy consumption for an autotrophic denitrifying biocathode<\/span><\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"elementor_header_footer","format":"standard","meta":{"footnotes":""},"categories":[64],"tags":[],"class_list":["post-11578","post","type-post","status-publish","format-standard","hentry","category-articles-ca"],"_links":{"self":[{"href":"https:\/\/lequia-udg.com\/ca\/wp-json\/wp\/v2\/posts\/11578","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/lequia-udg.com\/ca\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/lequia-udg.com\/ca\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/lequia-udg.com\/ca\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/lequia-udg.com\/ca\/wp-json\/wp\/v2\/comments?post=11578"}],"version-history":[{"count":1,"href":"https:\/\/lequia-udg.com\/ca\/wp-json\/wp\/v2\/posts\/11578\/revisions"}],"predecessor-version":[{"id":11579,"href":"https:\/\/lequia-udg.com\/ca\/wp-json\/wp\/v2\/posts\/11578\/revisions\/11579"}],"wp:attachment":[{"href":"https:\/\/lequia-udg.com\/ca\/wp-json\/wp\/v2\/media?parent=11578"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/lequia-udg.com\/ca\/wp-json\/wp\/v2\/categories?post=11578"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/lequia-udg.com\/ca\/wp-json\/wp\/v2\/tags?post=11578"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}